| Journal of Electron Spectroscopy and Related Phenomena | ||
| Volume 108, Issues 1-3 | ||
| July 2000 | ||
| Pages 141-151 | ||
PII: S0368-2048(00)00137-7
Copyright © 2000 Elsevier Science B.V. All rights reserved.
Excited state photoelectron spectroscopy on molecular aggregates containing aromatic molecules
C. G. Eisenhardt
, M. Oppel and H. Baumgärtel1,
Institut für Chemie, Freie Universität Berlin, D-14195 Berlin, Germany
Available online 24 July 2000.
The photoelectron spectra of anisole and its van der Waals aggregates with argon (1:1 and 1:2) or carbon dioxide (1:1) have been measured using resonant two-photon laser ionization and a magnetic bottle spectrometer. The influence of the aggregation toward the intramolecular vibrations is discussed. The evaluation of the photoelectron spectra suggests that two different isomers of the anisole¯argon (1:2) aggregate exist in the supersonic beam.
Author Keywords: Molecular aggregates; Photoelectron spectroscopy; Anisole; Intramolecular vibration
1 Also Corresponding author.
Corresponding author. Tel.: +49-30-838-52095; fax: +49-30-838-52717