Organic and Macromolecular Chemistry
Freie Universität Berlin Fachbereich Biology, Chemie, Pharmazie Institut für Chemie
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148

Beinhoff, M.; Karakaya, B.; Schlüter, A. D.
"Synthesis of low generation phenylene alkylene dendrons as non-polar building blocks for a dendrimer construction set"
Synthesis, 2003, 79-90.
Keywords Dendrimers, dendrons, Suzuki-Miyaura cross-coupling, iodo desilylation, building blocks  
   
Abstract The gram scale syntheses of first and second generation (G1 and G2) dendrons 1, 2, 3, 4, and 35, based on aryl and alkyl moieties, by Suzuki-Miyaura cross-coupling are presented. Both a divergent and an accelerated convergent route are applied. In addition first results on the synthesis of hyperbranched oligomers of AB2 monomer 19 are reported.