Organic and Macromolecular Chemistry
Freie Universität Berlin Fachbereich Biology, Chemie, Pharmazie Institut für Chemie
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Neudorff, W. D.; Schulte, N.; Lentz, D.; Schlüter, A.D.
"8,9-Dihydrofluoranthenes as Building Blocks for the Synthesis of Extended Polycyclic Aromatic Hydrocarbons (PAHs)"
Org. Letters
2001, 3, 3115-3118

Keywords Arines, PAH, fluoranthenes, fullerenes  
   
Abstract The synthesis of phenyl substituted 8,9-dibromofluoranthene and p-dodecylphenyl substituted 8,9-fluoranthene anthranilic acid is presented. Their synthetic potential as 8,9-didehydrofluoranthene precursors is demonstrated in combination with a new biscyclopentadienone by the synthesis of novel phenyl substituted PAHs with up to 14 annulated rings. The crystal structure of 7,16-diphenylfluorantheno[8,9-k]fluoranthene is given