Organic and Macromolecular Chemistry
Freie Universität Berlin Fachbereich Biology, Chemie, Pharmazie Institut für Chemie
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125

Manickam, G.; Schlüter, A.D.
"Synthesis of Oligo(het)arylene Building Blocks with Bi- and Terpyridine Units"
Eur. J. Org. Chem. 2000, 3475-3481
Keywords Suzuki cross coupling, Stille cross coupling, bipyridines, terpyridines, supramolecular chemistry  
 

 
Abstract The 330 mg to 12 g scale synthesis of a variety of arylene (3,5-8) and hetarylene building blocks with bipyridine (16,17,19) and terpyridine units (21-23,25) by and for transition metal mediated cross-coupling reactions is reported. All these compounds carry hexyloxymethyl substituents mainly for solubility reasons.