Organic and Macromolecular Chemistry
Freie Universität Berlin Fachbereich Biology, Chemie, Pharmazie Institut für Chemie
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Henze, O.; Lentz, D.; Schlüter, A.D.
"Synthesis and a X-ray structure of soluble phenylacetylene macrocycles with two opposing bipyridine donor sites"
Chem. Eur. J.
2000, 6, 2362 - 2367

Keywords bipyridines, cross-coupling, heterocycles, macrocycles, modular chemistry, supramolecular chemistry  
   
Abstract The 330 mg to 12 g scale synthesis of a variety of arylene (3,5-8) and hetarylene building blocks with bipyridine (16,17,19) and terpyridine units (21-23,25) by and for transition metal mediated cross-coupling reactions is reported. All these compounds carry hexyloxymethyl substituents mainly for solubility reasons.