Organic and Macromolecular Chemistry
Freie Universität Berlin Fachbereich Biology, Chemie, Pharmazie Institut für Chemie
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119

Manickam, G.; Schlüter, A.D.
"New Parts for a Construction Set of Bifunctional Oligo(het)arylene Building Blocks for Modular Chemistry"
Synthesis 2000, 3, 442-446.
Keywords Suzuki cross-coupling, Stille cross-coupling, supramolecular chemistry, pyridines, modular chemistry
 
 
Abstract The 100 mg to 5 g scale synthesis of a variety of arylene (6, 11, 13) and hetarylene building blocks (15, 17, 18) by and for Suzuki/Stille type cross-coupling reactions is reported. These building blocks carry solubilizing hexyloxymethyl substituents as well as boronic acid ester and Br/I functionalities. This widens the already existing construction set for the modular chemistry approach to shape persistent and functional compounds on the nanometer scale considerably.